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Spin-powered crystals dramatically improve water splitting process for clean hydrogen production by StuffsEarth - StuffsEarth
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Alienx
November 25, 2024
Crystal- and electronic-structure chirality of RhSi, RhSn and RhBiS. a , Illustration of the intrinsically chiral structure. Handedness can be distinguished by considering the helix formed by Rh atoms. Large (gray) and small (blue and red) arrows represent the current flow direction and induced spin polarization around Rh, respectively. b , Illustration of the spin texture on the Fermi surfaces around the Γ -point. Lattice chirality leads to a monopole-like spin texture, which gives rise to spin polarization when a current flows through the crystal. c , Single-crystal XRD pattern of the (0kl ) planes in the reciprocal lattice of RhBiS. The diffraction spots are consistent with the P 21 3 space group. d , Laue diffraction pattern of RhBiS (black dots) superimposed on a theoretically simulated pattern (red dots) of the (100) surface. e , STEM image of RhBiS. f , Illustration of the RhBiS crystal structure on the (111) surface with a helical arrangement of Rh atoms along the (111) direction. Yellow, pink and gray spheres represent Rh, Bi and S, respectively. Credit: Nature Energy (2024). DOI: 10.1038/s41560-024-01674-9
Water splitting—breaking water molecules into hydrogen and oxygen—is a promising pathway to sustainable energy. However, this process has long been challenged by the slow chemical kinetics of the oxygen evolution reaction that make hydrogen production inefficient and costly.
An international research team has now uncovered a solution. By using special crystals with unique intrinsic “chiral” structures—meaning they have a distinctive left or right-handed atomic arrangement—researchers have dramatically improved the water splitting process.
The findings are published in the journal Nature Energy .
The topological chiral crystals, composed of rhodium and elements like silicon, tin, and bismuth, possess an extraordinary ability to manipulate electron spin. This quantum mechanical property allows electron transfer to oxygen generation in a highly efficient manner, significantly accelerating the overall chemical reaction.
“These crystals are essentially quantum machines,” says Dr. Xia Wang, lead researcher from the Max Planck Institute for Chemical Physics of Solids. “By leveraging the unique spin properties of electrons, we’ve created a catalyst that outperforms traditional materials by a factor of 200.”
Prof. Binghai Yan adds, “We are aware that our catalysts still contain rare elements, however we are confident that based on our design scheme we will come up soon with highly efficient and also sustainable catalysts.”
This breakthrough isn’t just a scientific curiosity—it represents a potential leap forward in renewable energy technology. The new catalyst could make hydrogen production faster, more efficient, and more economically viable, bringing us closer to a clean energy future.
The research, conducted by scientists from the Max Planck Institute CPfS and the Weizmann Institute of Science, demonstrates how cutting-edge quantum physics can solve real-world energy challenges.
More information:
Xia Wang et al, Topological semimetals with intrinsic chirality as spin-controlling electrocatalysts for the oxygen evolution reaction, Nature Energy (2024). DOI: 10.1038/s41560-024-01674-9
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